Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

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      76 044
      1, 40
      T. LIPPMANN, G. MANN, (Inst. f. Org. Chem. der Univ. Leipzig, Talstr. 35, D-04103 Leipzig, Germany). Chromatography of diastereomeric calix(4)arenes. (German). GIT Fachz. Lab. 39, 203 - 207 (1995). TLC of diastereomeric calix(4)arenes on silica with dichloromethane - acetone in different ratios, e.g. 30
      Classification: 7, 38
      82 200
      Thin-layer chromatography using synthetic polymers imprinted with quinine as chiral stationary phase
      R. SUEDEE*, C. SONGKRAM, A. PETMOREEKUL, S. SANGKUNAKUP, S. SANKASA, N. KONGYARIT, (*Dept. of Pharm. Chem., Fac. of Pharm. Sci., Prince of Songkla Univ., Songkhla 90110, Thailand)

      J. Planar Chromatogr. 11, 272-276 (1998). TLC of diastereomers (including quinine - quinidine and cinchonine - cinchonidine) and enantiomers (including pseudoephedrine, ephedrine, norephedrine, and epinephrine) on synthetic polymers, imprinted with quinine as chiral stationary phase. Description of the preparation of Molecularly Imprinted Polymers (MIPs). The mobile phases contained different concentrations of acetic acid (0, 1, 5, 10%) in either methanol or acetonitrile. Detection under UV 366 nm.

      Keywords:
      Classification: 38
      87 165
      Direct resolution of aromatic alcohols by planar chromatography on tribenzoylcellulose as chiral stationary phase
      L. LEPRI, M. Del BUBBA, A. CINCINELLI, L. BODDI*, (Dept. of Public Health, Epidemiology and Environmental Anal. Chem., Univ. of Florence, Via G. Capponi 9, 50121 Florence, Italy)

      J. Planar Chromatogr. 14, 134-136 (2001). TLC of 14 racemic alcohols (1-acenaphthol, a-tetralol, 1-indanol, Troger's base, trans-2-phenyl-1-cyclohexanol, 1-phenyl-ethanol, 1-phenyl-propanol, 1-phenyl-1,2-ethanediol, 1-phenyl-1,3-propanediol, 2-phenyl-2-butanol, 2-phenyl-1,2-propanediol, 2-phenyl-3-butyn-2-ol, 1-phenyl-2-propanol, 1-phenyl-2-butanol) on plates prepared from mixtures of CTB (cellulose tribenzoate) and silica gel. Mixtures of ethanol - water and of n-hexane - 2-propanol were investigated as mobile phases. Visualization by exposure to iodine vapor for 24 h. Troger's base was detected under UV 254 nm. Densitometric measurements of a-tetralol and 1-indanol were performed.

      Keywords:
      Classification: 6, 38
      99 173
      Chiral Separations of ibuprofen and propanolol by TLC
      M. SAJEWICZ, R. PIETKA, Teresa KOWALSKA* (*Institute of Chemistry, Silesian University, 9 Szkolna Street, Katowice, Poland; kowalska@us.edu.pl)

      A study of the mechanism and thermodynamics of retention. J. Liq. Chromatogr. Relat. Technol. 28, 2499-2513 (2005). TLC of R,S-(+/-)-ibuprofen and S-(+)-ibuprofen on silica gel prewashed with methanol - water 9:1 and impregnated with a 0.03 mol/L methanolic solution of L-arginine by dipping. Separation with acetonitrile - methanol - water 5:1:1 and several drops of acetic acid to adjust the pH to 4.8. Two dimensional development with the same mobile phase in the first direction, followed by drying and application of the S-(+)-enantiomer and development in the second direction. Densitometric evaluation at 210 nm. Chiral separation of propanolol with acetonitrile - methanol 15:4 containing ammonia for one and two dimensional separation.

      Classification: 2b, 32a, 38
      101 106
      TLC and polarimetric investigation of the oscillatory in-vitro chiral inversion of L-alanine
      M. SAJEWICZ, D. KRONENBACH, M. GONTARSKA, Teresa KOWALSKA* (*Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006 Katowice, Poland; kowalska@uranos.cto.us.edu.pl)

      J. Planar Chromatogr. 21, 43-47 (2008). TLC and polarimetry was used to investigate the tendency of L-alanine to undergo oscillatory in-vitro chiral inversion when dissolved in neutral, acidic, and basic solvents. The influences of temperature and sample mixing were investigated as well. It was confirmed that L-alanine undergoes chiral inversion. TLC of L-alanine on silica gel, prewashed with methanol - water 9:1, and impregnated twice with aqueous copper sulfate solution and L-proline in water - methanol 9:1. Development with 2-propanol - acetonitrile - water 6:2:3 at 22 °C. Detection by dipping in freshly prepared 0.2 % methanolic ninhydrin solution, followed by heating at 100-110 °C for 10 min. Quantitation by densitometry at 540 nm.

      Classification: 38
      107 159
      Development and validation of a method for the enantioseparation of oxybutynin chloride by HPTLC
      P. SITADEVI, P. RAO (Analytical Chemistry Div., Indian Institute of Chemical Technology, Tarnaka, Hyderabad 500007, India, sitadevi@iict.res.in)

      Analytical Chemistry, An Indian Journal 9(3) (2010). HPTLC of a racemic mixture of oxybutynin chloride on chiral phase with toluene – acetone – methanol 8:1:1. Both enantiomers were well separated with hRf values of 47 and 63. The identity of the isomers was established by on-line UV, NMR and MS data. The method was validated using NP-TLC and the same mobile phase. The method was linear in the range of 50-350 µg/band with a recovery of 98.2-101.7 %.

      Classification: 38
      120 052
      Thin layer chromatographic resolution of some ?-adrenolytics and a ?2-agonist using bovine serum albumin as chiral additive in stationary phase
      P. MALIK, R. BHUSHAN* (*Dep. of Chem., Indian Inst. of Technol. Roorkee, Roorkee-247667, India, rbushfcy54@gmail.com)

      J. Chromatogr. Sci. 56 (1), 92-98 (2018). TLC for direct enantiomeric resolution of the racemic β-adrenolytics bisoprolol (1), atenolol (2), propranolol (3), salbutamol (4) and carvedilol (5) by TLC using bovine serum albumin (BSA) as chiral additive in the stationary phase and with different compositions of simple organic solvents without buffer or inorganic ions. Systematic investigation of the effect of variation in pH, temperature, amount of BSA as the additive, and composition of mobile phase on resolution. Detection by exposure to iodine vapors. The five entantiomers were separated in the elution order (1), (2), (3), (4), and (5). The LOD was 0.7, 1.2, 0.8, 1.6 and 0.9 μg/zone for (1), (2), (3), (4), and (5), respectively.

      Classification: 11c, 32c, 38
      66 029
      (Development of silica gel thin-layer plate for the separation and analysis of optical antipodes) (Japanese)
      H. OHRUI, (Coll. Agric., Tohoku Univ., Sendai, Japan)

      Bunseki (J. Jap. Anal.) 6, 470-471 (1989). A review with 5 references on the determination of optical purity by NMR and HPLC, and on TLC separation of optical isomers based on octadecyl-silylated silica impregnated with chiral copper complexes.

      Keywords: review
      Classification: 3b, 38