Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

  • Full text search: Enter a keyword, e.g. an author's name, a substance, a technique, a reagent or a term and see all related publications
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Registered users can create a tailor made PDF of selected articles throughout CCBS search – simply use the cart icon on the right hand of each abstract to create your individual selection of abstracts. You can export your saved items to PDF by clicking the download icon.

      65 015
      Resolution and separation capacity in planar chromatography
      C.F. POOLE, S.K. POOLE, (Dept. Chemistry, Wayne State University, Detroit, Michigan 48202, USA )

      J. Planar Chromatogr. 2, 165-168 (1989). Practice of planar chromatography. Equations are given for resolution, plate height, separation number and best number of developments producing maximum separation.

      Keywords:
      Classification: 2a
      69 014
      Mechanism of liquid adsorption chromatography in thin-layer chromatography with ternary mobile phases
      B. OSCIK-MENDYK, (Fac. Chem., Maria-Curie-Sklodowska Univ., Pl. Marii Curie Sklodowskiej 3, 20-031 Lublin, Poland)

      J. Chromatogr. 550, 645-656 (1991). Discussion of a model chromatographic process which takes into account molecular association in the mobile phase. Application of the model to the study of the association effects in liquid adsorption chromatography with ternary mobile phases. Use of Jaroniec’s equation in description of molecular interactions

      Keywords:
      Classification: 2a
      79 015
      A practical look at planar chromatography
      I. OJANPERÄ*, J. VUORELA, (*Dept. of For. Med., P.O. Box 40, FIN-00014 University of Helsinki)

      (Finnish). Kemia-Kemi 24, 224-228 (1997). Advantages of HPTLC, AMD, OPLC and a special spectrum library are described. According to the authors important fields that utilize TLC are pharmaceutical analysis, toxicology and pharmacognosy.

      Keywords:
      Classification: 2a
      96 002
      Surfing silica surfaces superciliously
      P.G. RIGHETTI, Cecilia GELFI, R. SEBASTIANO, A. CITTERIO* (*Department of Chemistry, Materials and Engineering Chemistry, Politecnico di Milano, via Mancinelli 7, Milano 20131, Italy)

      J. Chromatogr. A 1053 (1-2), 15-26 (2004). The mini-review summarizes the develoment of different classes of novel quaternarized heterocyclic compounds able to modulate and reverse the electroendoosmotic flow (EOF) in a most peculiar manner. The first class comprises mono-salt compounds, with the determinant omega-iodoalkyl chains of different lengths (typically C4-C8), able to be adsorbed by silicas at alkaline pH and spontaneously alkylate ionised silanols, thus becoming covalently affixed to it. The second class is constituted by di-salt compounds, attached at the termini of an alkyl chain of variable lengths (typically C4-C8). This second class is unable to bind covalently silica surfaces although in thin-layer chromatography it exhibits an extraordinary affinity for silica beads, contrary to the first one. On the basis of the strikingly different behaviour structural rules are derived for the minimum requirements for general classes of amines to bind to silica walls and modify EOF. For compounds unable to bind covalently to the wall, the most important structural motif is two quaternary nitrogens spaced apart by a C4 chain: this seems to be the average distance (i.e. 0.8 nm) between two adjacent, ionized silanols for a snug fit. The other structural binding motif is the "hydrophobic decoration", i.e. the ratio of charged groups to alkyl residue in the various amines; amines with high levels of such alkane groups (i.e. with higher hydrophobicity), seem to bind more tenaciously to the wall, probably due to hydrophobic interaction not to the wall but among the amine derivatives themselves when carpeting the silica.

      Keywords: review
      Classification: 1, 2a
      115 005
      Effects of addition of ion-pair reagent to the mobile phase on electroosmotic flow velocity in pressurized planar electrochromatography
      Aneta HALKA-GRYSINSKA, P. W. PLOCHARZ, Ewa SKWAREK, W. JANUSZ, T. D. DZIDO* (*Department of Physical Chemistry, Medical University of Lublin, 4a W. Chodzki Str., 20-093 Lublin, Poland, tadeusz.dzido@umlub.pl)

      J. Planar Chromatogr. 28, 133-138 (2015). HPTLC on RP-18W phase with acetonitrile - water 1:3 with acetic buffer (4 mM) and with or without ion-pair reagent (sodium-1-heptane sulfonate, tetrabutylammonium chloride, and bis(2-ethylhexyl)hydrogen phosphate). The influence of the addition of different ion-pair reagents to the mobile phase on the velocity of the electroosmotic flow in pressurized planar electrochromatography was examined. The results demonstrate that in pressurized planar electrochromatography, a small addition of ion-pair reagents affects the selectivity of separation.

      Keywords:
      Classification: 2b
      68 011
      Theory and mechanism of thin-layer chromatography
      T. KOWALSKA, (Silesian Univ., Katowice, Poland)

      Chromatogr. Sci. 55, 43-69 (1991). A review with 33 references. Discussion of physical phenomena important for the chromatographic process, as well as main concepts for efficiency of separation. Also review of semiempirical models of partitions and adsorption chromatography and discussion of their usefulness in every day lab practise.

      Keywords: review
      Classification: 2b
      73 011
      On the mechanism of retention in adsorption TLC with isopropanol - n aliphatic hydrocarbon eluents
      T. KOWALSKA, B. KLAMA, (Inst. of chemistry, silesian Univ., 9 Szkolna Str., PL-40006 Katowice Poland)

      J. Planar Chromatogr. 7, 63-69 (1994). Investigation of the mechanism of solute retention in silica gel adsorption TLC using three different mobile phases, i.e. isopropanol - hexane, isopropanol - heptane, isopropanol - octane mixtures. The empirical results were compared with predictions based on the classical displacement model, and on the so-called alternative model which concentrates on intermolecular interactions between the components of mixed mobile phases.

      Keywords:
      Classification: 2b
      98 012
      Does the Kubelka-Munk theory describe TLC evaluations correctly? J
      B. SPANGENBERG (University of Applied Sciences Offenburg, Badstrasse 24, 77625 Offenburg, Germany)

      Planar Chromatogr. 19, 332-341 (2006). In TLC the development step distributes the sample throughout the layer. The essential reqirement for quantitative TLC is a constant sample distribution in each sample spot. The paper shows that quantitative TLC is possible even if the concentration of the sample is not constant. In the absence of uniform sample distribution classical Kubelka-Munk theory must be extended. The extended theory presented is not only capable of describing asymmetrical scattering in TLC layers but also includes a formula for absorption and fluorescence in diode-array TLC. With this new formula all different formulas for diode-array thin-layer chromatographic evaluation are combined in one expression.

      Keywords:
      Classification: 2b