Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

  • Full text search: Enter a keyword, e.g. an author's name, a substance, a technique, a reagent or a term and see all related publications
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      96 011
      Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data
      M. M. Natic*, R. M. Baosic, D. M. Milojkovic-Opsenica, Z. Lj. Tesic* (*Faculty of Chemistry, University of Belgrade, P. O. Box 158, 11001 Belgrade, Serbia and Montenegro)

      J. Planar Chromatogr. 18, 344-348 (2005). TLC of beta-diketonato complexes of the type M(acac) 3-n(phacphac)n and M(acac)3-n(phSacphSac)n, where M represents cobalt(III) or chromium(III), acac is the pentanedionato ion, phacphac the 1,3-diphenyl-1,3-propanedionato ion, and phSacphSac the 3-mercato-1,3-diphenylprop-2-en-1-thione ion (n= 0-3), on RP-18 with mixtures of tetrahydrofuran, acetonitrile, or acetone (as organic modifier) with water.

      Classification: 2c
      96 055
      Mobile-phase velocity - a tool for separation of alkaloids by OPLC
      I. Malinowska, M. Gadzikowska, Monika Waksmundzka-Hajnos*, A. Kramek (*Department of Inorganic Chemistry, Medical University, Staszica 6, 20-081 Lublin, Poland)

      J. Planar Chromatogr. 18, 176-180 (2005). OPLC separation of alkaloids on silica gel using different mobile-phase velocities from 100 to 400 µL/min and investigation of this effect on properties such as retardation factors, reproducibility, efficiency, number of theoretical plates, HETP, and resolution. OPLC of tertiary alkaloid standards (allocryptopine, protopine, chelidonine) and quaternary alkaloid standards (chelerythrine, chelilutine, sanguinarine, and chelirubine) on silica gel with toluene - ethyl acetate - methanol 14:3:3 for tertiary alkaloids and toluene - ethyl acetate - methanol 83:15:2 for quaternary alkaloids.

      Classification: 22
      96 087
      Determination of emodin and phenolic acids in the petioles of Rheum undulatum and Rheum rhaponticum
      H. Danuta Smolarz*, E. Medynska, G. Matysik (*Department of Pharmaceutical Botany, Medical University, 1 Chodzki Str., Lublin, Poland)

      J. Planar Chromatogr. 18, 319-322 (2005). HPTLC of emodin and phenolic acids (protocatechuic, homoprotocatechuic, caffeic, syringic, vanillic, ferulic, p-hydroxyphenylacetic, alpha-resorcylic, p-coumaric, gallic and ellagic acid) on silica gel in horizontal chambers with toluene - dichloromethane - ethyl acetate 4:4:1. Also two-dimensional TLC of phenolic acids on cellulose with benzene - methanol - acetic acid - acetonitrile 16:2:1:1 in the first direction and sodium formate - formic acid - water 10:1:200 in the second direction. After drying the chromatograms were observed under UV light at 254 nm before and after treatment with ammonia vapor. Derivatization was performed by spraying with either diazotized sulfanilic acid in 20 % sodium carbonate solution or with 2 % aqueous iron(III) chloride. Detection limits between 10 and 64 ng. Videodocumentation and quantitation by densitometry.

      Classification: 11a, 32e
      96 128
      Examination of the hydrophobicity of ACE inhibitors and their active metabolites by salting-out thin-layer chromatography
      J.V. ODOVIC, B.B. STOJIMIROVIC, Mirjana B. ALEKSIC*, D. M. MILOJKOVIC-OPSENICA, Z.L. TESIC (*Faculty of Pharmacy, University of Belgrade, P. O. Box 146, 11001 Belgrade, Serbia and Montenegro)

      J. Planar Chromatogr. 18, 98-103 (2005). Salting-out TLC (SO TLC) of five ACE inhibitors and their active degradation products (enalapril, enalaprilat, quinapril, quinaprilat, fosinopril, fosinoprilat, lisinopril, cilazapril, cilazaprilat) on silica gel, cellulose, and polyacrylonitrile with aqueous ammonium sulfate solutions of different concentrations. Increasing the salt concentration in the mobile phase led to increased RM values for all substances. For comparison TLC on RP-18 with methanol - water. Detection by exposure to iodine vapour.

      Classification: 32a
      97 002
      Use of RP-TLC for determination of log P of isomeric chalcones and cyclic chalcone analogues
      Z. Rozmer, P. Perjési*, K. Takács-Novák (*Institute of Pharmaceutical Chemistry, University of Pécs, Rókus str. 2, H-7624 Pécs, Hungary)

      J. Planar Chromatogr. 19, 124-128 (2006). Determination of log P values of 29 biologically active chalcone and cyclic chalcone analogues E-2-(X-benzylidene)-1-indanones and E-2-(X-benzylidene)-1-tetralones by an optimized and validated RP-TLC method. RP-TLC was performed on silanized silica gel with methanol - water 3:2. The experimentally determined log P(TLC) values were compared with the log P values predicted by use of the CLOGP program.

      Classification: 2c
      97 031
      Separation of selected bile acids
      Alina PYKA*, M. DOLOWY (*Department of Analytical Chemistry, Faculty of Pharmacy, Silesian Academy of Medicine, 4 Jagiellonska St., PL-41-200 Sosnowiec, Poland; alinapyka@wp.pl)

      IV. Comparison of separation of studied bile acids by the use of cluster analysis. J. Liq. Chrom. & Rel. Technol. 27, 2987-2995 (2004). TLC of bile acids (cholic, glycocholic, glycolithocholic, deoxycholic, chenodeoxycholic, glycodeoxycholic, and lithocholic acid) on silica gel and a mixture of silica gel and Kieselguhr with n-hexane - ethyl acetate - acetic acid in various volume compositions. Detection with 10 % aqueous sulfuric acid followed by heating at 120 °C for 20 min. On silica gel the separation of glycocholic from glycodeoxycholic acid was difficult, on the mixed silica gel - Kieselguhr layer the separation of cholic acid from glycolithocholic acid. The obtained results indicate that similar analysis can be an alternative method for the estimation of chromatographic separations of studied bile acids.

      Classification: 13d
      97 069
      Stability-indicating methods for the determination of linezolid in the presence of its alkaline-induced degradation products
      L.I. BEBAWY (National Organization for Drug Control and Research, 6 Hussen Kamal el Deen, Ben-el-sariat, Dokki, Giza 12311, Egypt )

      Talanta 60 (5), 945-953 (2003). TLC of linezolid from its alkaline degradation product on silica gel with isobutanol - ammonia 9:1. Quantitative determination by densitometric measurement at 244 nm. The proposed method and two other methods (based on spectrophotometry) were successfully applied to the determination of the drug in bulk powder, in laboratory prepared mixtures with its degradation product and in commercial tablets.

      Classification: 32c
      97 103
      Preparative isolation of cannabinoids from Cannabis sativa by centrifugal partition chromatography
      A. Hazekamp, R. Simons, A. Peltenburg-Looman, M. Sengers, R. van Zweden, R. Verpoorte (*Division of Pharmacognosy, Institut of Biology, Leiden University, Einsteinweg 55, 2300 RA, Leiden, The Netherlands; ahazekamp@rocketmail.com)

      J. Liq. Chrom. & Rel. Technol. 27, 2421-2439 (2004). TLC of e. g. delta8-tetrahydrocannabinol, cannabigerol, cannabigerolic acid, cannabidiolic acid, and (-)-delta9-(trans)-tetrahydrocannabinolic acid on RP18 with methanol - 5 % acetic acid 19:1. Detection under UV light at 254 nm and by spraying with modified anisaldehyde - sulfuric acid spray reagent. For selective detection of cannabinoids, the plate was sprayed with 0.5 % fast blue B salt in water, followed by 0.1 M NaOH.

      Classification: 32e
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