Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

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      71 191
      Salting-out thin-layer chromatography of transition metal complexes
      G. VUCKOVIC, O. MILZEVIC, T.J. JANJIC, M.B. CELAP, (Fac. Chem., Univ. Belgrade, P.O. Box 550, 11001 Belgrade, Yugoslavia)

      I. Investigation of the behaviour of mixed aminocarboxylato cobalt(III) complexes on silica gel. J. Chromatogr. 609, 427-431 (1992). Investigation of 24 mixed aminocarboxylato cobalt(III) complexes of anionic and neutral types, containing nitro ligands with or without ammonia ligands and belonging to six homologous series by salting-out TLC on silica. Aqueous ammonium sulfate solution in water. Proposal of a mechanism based on hydrophobic interaction between the sorbate and the sorbent.

      Keywords:
      Classification: 33a
      76 206
      (Study of Co(II), Cu(II), Zn(II), Pb(II), Mn(II) and Ni(II) as their glyoxylic acid thiosemicarbozone complexes by thin-layer chromatography
      H. LI (Li Huaina), J. YU (Yu Jinmao), F. LI (Li Feng), J. TIAN (Tian Junlian), C. LIU (Liu Cui), (Dept. Chem., Qufu Norm. Univ., Qufu 273165, P.R. China)

      Chinese J. Chromatogr. (Sepu) 13, 203-204 (1995). TLC on silica with acetone - ethyl acetate - methanol - water. Detection by exposure to iodine vapors. Calculation of the Rf values. Rf (Co) > Rf (Pb) > Rf (Un) > Rf (Cu) > Rf (Ni) > Rf (Mu).

      Keywords:
      Classification: 33a
      80 012
      Chromatographic separation of inorganic ions on thin-layers of lanthanum silicate ion-exchanger
      S.W. HUSAIN*, A. MIRZAIE, (*Chem. Dept., Fac. Sci., Univ. Tarbiat Moallem, 49 Mofatteh Avenue, Tehran - 15614, Iran)

      Chromatographia 45, 347-350 (1997). Use of the thin-layers of lanthanum silicate to study the chromatographic behavior of 28 metal ions in aqueous and mixed systems. Discussion of fast ternary and binary separations and various others.

      Keywords:
      Classification: 3b, 33a
      87 159
      Reversed-phase TLC of 3d metal ions on silica gel GF254 impregnated with silicone fluid DC200, tri-aryl phosphate, and tri-n-butyl phosphate and with DMSO-HNO3 mobile phases
      S.D. SHARMA*, S.C. SHARMA, C. SHARMA, (*Anal. Res. Lab., Dept. of Chem., Hindu College, B-3, Jigar Colony, Moradabad-244001, India)

      J. Planar Chromatogr. 14, 16-20 (2001). RP-TLC of 3d metal ions (e.g. VO2+, Fe3+, Ti4+, Mn2+, Zn2+,) on silica gel impregnated with silicone fluid DC200, tri-aryl phosphate, and tri-n-butyl phosphate with mixtures of DMSO and HNO3. The most effective eluents prepared from DMSO and 1 M HNO3 were mixtures in which the concentration of the acid is between 0.1 and 0.7 M.

      Keywords:
      Classification: 33a
      98 118
      TLC separation of metal ions using di(n-butyl)dithiophosphoric acid and neutral organophosphorus ligands
      M. CURTUI, Maria-Loredana SORAN* (*National Institute of Research and Development for Isotopic nad Molecular Technology, 72-103 Donath Street, 400293 Cluj-Napoca, Romania)

      J. Planar Chromatogr. 19, 297-301 (2006). TLC of U(VI), Th(IV), the lanthanides Ln(III), (La(III), Ce(III), Pr(III), Sm(III), Gd(III), Er(III)), Co(II), Ni(II), and Cu(II) on silica gel using mobile phases containing tributylphosphate, trioctylphosphine oxide (TOPO), and di(n-butyl)dithiophosphoric acid (HDBDTP). The results obtained showed that the retention factors of U(VI), Th(IV), and Ln(III) are enhanced when a mixture of HDBDTP and TOPO is used. TLC on silica gel with xylene - ethyl methyl ketone - N,N-dimethylformamide 16:2:1 in an unsaturated chamber. Detection with 0.05 % arsenazo(II) for U(VI), Th(IV), and Ln(III) and with 0.1 % rubeanic acid in ethanol for Co(II), Ni(II), and Cu(II).

      Keywords:
      Classification: 33a
      119 108
      Separation of transition and heavy metals using stationary phase gradients and thin layer chromatography
      S.L. STEGALL, K.M. ASHRAF, J.R. MOYE, D.A. HIGGINS, M.M. COLLINSON* (*Dep. of Chem., Virginia Commonwealth Univ., Richmond, VA 23284-2006, USA)

      J. Chromatogr. A 1446, 141-148 (2016). Investigation of stationary phase gradients for chelation TLC as a tool to separate a mixture of metal ions. Preparation of the gradient stationary phases using controlled rate infusion from precursors containing mono-, bi-, and tri-dentate ligands, specifically 3-aminopropyltriethoxysilane, N-[3-(trimethoxysilyl)propyl] ethylenediamine, and N-[3-(trimethoxysilyl)propyl] diethylenetriamine. Confirmation of the presence and the extent of gradient formation using N1s X-ray photoelectron spectroscopy. The results showed that the degree of modification was dependent on the aminosilane precursor, its concentration, and the rate of infusion. Comparison of the separation of four transition and heavy metals (Co2+, Pb2+, Cu2+, and Fe3+) by TLC on gradient and uniformly modified plates with a mobile phase containing a stronger chelating agent, ethylenediaminetetraacetic acid. Manipulation of the retention of the metal ions by varying the surface concentration of the chelating ligands. The order of retention on unmodified plates and on plates modified with a monodentate ligand was Fe3+>Cu2+∼Pb2+∼Co2+, while the order of retention on plates modified with bi- and tri-dentate ligands was Fe3+>Cu2+>Pb2+∼Co2+. Fe3+ and Cu2+ were more sensitive to the concentration of chelating ligand on the surface and showed lower hRf values with increasing ligand concentration than Pb2+ and Co2+. Complete separation was achieved using a high concentration of the tridentate ligand coupled with a longer time for modification, giving a retention order of Fe3+ > Cu2+ > Co2+ > Pb2+.

      Classification: 3d, 33a
      58 189
      Thin-layer chromatography method for the investigations of Re(VII), Mo(VI) and V(V) ion mixtures
      D.S. GAIBAKIAN, J.K. ROZYLO, M. JANICKA

      J. Liquid Chrom. 8, 2969-2989 (1985). Separation of Re(VII), Mo(VI) and V(V) ions on alumina with aliphatic alcohols - HCl mixtures. Visualization with 10 % solution of Tin(II) chloride in 6 N HCl and with 50 % aq. NH4SCN solution.

      Keywords:
      Classification: 33a
      60 219
      (Separation of the rare earths by thin-layer chromatography
      H. LUO (Luo Huanguang), R. XIE (Xie Ruiming), K. ZHENG (Zheng Keqiu), (Lab. Anal. Chem., Wuhan Univ., Wuhan, P.R. China). Chinese J. Nuc. Chem. & Rad. Chem. 8, 185-188 (1986) (He Huaxue YuFangshe Huaxue). (Chinese)
      Keywords:
      Classification: 33a