Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

  • Full text search: Enter a keyword, e.g. an author's name, a substance, a technique, a reagent or a term and see all related publications
  • Browse and search by CBS classification: Select one of the 38 CBS classification categories where you want to search by a keyword
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Registered users can create a tailor made PDF of selected articles throughout CCBS search – simply use the cart icon on the right hand of each abstract to create your individual selection of abstracts. You can export your saved items to PDF by clicking the download icon.

      129 024
      Goldenrod root compounds active against crop pathogenic fungi
      D. KRÜZSELYI, J. BAKONYI, P. OTT, A. DARCSI, P. CSONTOS, G. MORLOCK, Agnes MORICZ* (*Plant Protection Institute, Centre for Agricultural Research, Eötvös Loránd Research Network (ELKH), 1022 Budapest, Hungary, moricz.agnes@atk.hu)

      J. Agric. Food Chem. 69, 12686-12694 (2021). HPTLC of 2Z,8Z- and 2E,8Z-matricaria esters in European goldenrod (Solidago virgaurea) and E- and Z-dehydromatricaria esters in grass-leaved goldenrod (Solidago graminifolia) and showy goldenrod (Solidago speciosa) on silica gel with n-hexane − acetone 17:3. Detection by dipping into mycelium suspension of F. avenaceum and B. sorokiniana, followed by incubation in a vapor chamber at 21 °C for 48−72 h. The lack of visible white (F. avenaceum) or dark gray (B. sorokiniana) fungal mycelia indicated the inhibition zones on the bioautograms. Compounds were further analyzed by high-resolution mass spectrometry and nuclear magnetic resonance spectroscopy.

      Classification: 4e, 28a
      129 003
      On-surface autosampling for liquid chromatography – mass spectrometry
      A. MEHL, W. SCHWACK, Gertrud E. MORLOCK* (*Institute of Nutritional Science, and Interdisciplinary Research Centre for Biosystems, Land Use and Nutrition, Justus Liebig University Giessen, Giessen, Germany; gertrud.morlock@uni-giessen.de)

      J Chromatogr A, 1641, 462334 (2021). Validation of a newly built (using 3D-printing) and newly configurated on-surface multi-purpose autosampler, called “autoTLC−LC−MS system”, developed for orthogonal hyphenation of normal phase HPTLC with reversed phase HPLC and high-resolution MS. Details and protocols are given for the construction, installation and numerical control software programming of this autosampler. HPTLC of antibiotics cefoperazone (third-generation cephalosporin), clindamycin (lincosamide), erythromycin A (macrolide), ipronidazole (nitro-imidazole), nafcillin (penam), sulfaquinoxaline (sulphonamide), tiamulin (pleuromutilin), and trimethoprim (DHFR inhibitor) on silica gel without development. Bioassay with Bacillus subtilis: bacterial suspension was sprayed onto the plate, which was  horizontally incubated for 2 h at 37°C in a humid box; afterwards, the plate was sprayed with 0.2% MTT solution, incubated again for 30 min at 37°C, dried for 10 min at 50°C, and documented under white light. The image was uploaded as a template in the updated TLC–MS managing software, so that by clicking on the zones of the image showing antibacterial activity, the corresponding zones of the untreated plate, placed on a newly designed plate holder, were sequentially eluted by the round elution head of the automatic sampler into the RP-18 endcapped HPLC monolithic column connected to a Quadrupole-Orbitrap mass spectrometer. For the elution from the plate and HPLC separation, a gradient was used (flow rate 0.2 - 0.5 mL/min, depending on the step), with different proportions of two mobile phases: A) 0.1 % formic acid and 4 mM ammonium formate in water; B) 0.1 % formic acid and 4 mM ammonium formate in methanol. After separation in the column, antibiotics directly underwent electrospray ionization in positive mode (voltage 3.5 kV, capillary temperature 320 °C, probe heater temperature 350 °C) and were detected by HRMS. For validation, the achieved ranges were 2.1–14.1 % for intra-day and 2.5–16.1 % for inter-day precisions.

      Classification: 4d, 4e, 28a
      128 076
      A validated quantification of triclosan in toothpaste using high‑performance thin‑layer chromatography and a 48‑bit flatbed scanner
      B. ANDERS, S. DOLL, B. SPANGENBERG* (*Institute of Process Engineering, Offenburg University of Applied Sciences: Hochschule Offenburg, Badstrasse 24, 77652 Offenburg, Germany, spangenberg@HS-Offenburg.de)

      J. Planar Chromatogr. 34, 203-209 (2021). HPTLC of triclosan in toothpaste on silica gel with n-heptane - methyl tert-butyl ether - acetic acid 920:80:1. Detection by spraying with 2,6-dichloroquinone-4-chloroimide in 50 mL methanol, followed by spraying with an aqueous sodium carbonate solution (1 g/10 mL). Plates were scanned using a flatbed scanner. The hRF value for triclosan was 22. Linearity was between 100 and 1000 ng/zone. The LOD and LOQ were 46 and 91 ng/zone, respectively. Average recovery was 93.2 %.

      Classification: 28a
      128 078
      Stability‑indicating high‑performance thin‑layer chromatography method for the simultaneous estimation of emtricitabine and tenofovir alafenamide fumarate
      A. KASHID*, R. KADAM (*Department of Pharmaceutical Chemistry, Sinhgad Technical Education Society, Sinhgad Institute of Pharmacy, Narhe, Pune 411041, India, arunkashid2006@gmail.com)

      J. Planar Chromatogr. 34, 253-261 (2021). HPTLC of emtricitabine (1) and tenofovir alafenamide fumarate (2) on silica gel with ethyl acetate - n-hexane - methanol - ammonia solution 20:20:10:1. Quantitative determination by absorbance measurement at 260 nm. Linearity was between 400 and 2000 ng/zone for (1) and 50 and 250 ng/zone for (2). Intermediate precisions were below 2 % (n=3). The LOD and LOQ were 29 and 87 ng/zone, respectively. Recovery was between 100 and 102 % for (1) and 100 and 103 % for (2).

      Classification: 28a
      128 079
      A rapid and highly sensitive stability‑indicating high‑performance thin‑layer chromatography technique for the determination of tedizolid phosphate with a classical univariate calibration
      P. ALAM*, F. SHAKEEL, M. ALQARNI, A. FOUDAH (*Department of Pharmacognosy, College of Pharmacy, Prince Sattam Bin Abdulaziz University, Al‑Kharj 11942, Saudi Arabia, prawez_pharma@yahoo.com)

      J. Planar Chromatogr. 34, 271-278 (2021). HPTLC of tedizolid phosphate on silica gel with chloroform - methanol 9:1. Quantitative determination by absorbance measurement at 300 nm. The hRF value for tedizolid phosphate was 46. Linearity was between 10 and 2000 ng/zone. Intermediate precisions were below 2 % (n=6). The LOD and LOQ were 3 and 10 ng/zone. Recovery was between 98.5 and 101.7 %.

      Classification: 28a
      128 080
      Development and validation of a high‑performance thin‑layer chromatography assay for the analysis of tacrolimus ointments
      M. ISLAM, J. KEAY, Y. HUSSENBOCUS, A. SVAGELJ, D. LAM, T. SOSTARIC, M. NGUYEN, L. LIM, S. SKETT, Cornelia LOCHER* (*Division of Pharmacy, School of Allied Health, University of Western Australia, Crawley, WA 6009, Australia, connie.Locher@uwa.edu.au)

      J. Planar Chromatogr. 34, 189-195 (2021). HPTLC of tacrolimus on silica gel with acetonitrile - ethyl acetate - glacial acetic acid 60:20:20:1. Detection by spraying with anisaldehyde reagent (0.5 mL of p-anisaldehyde was mixed with 10 mL of glacial acetic acid, 85 mL of methanol and 5 mL of sulfuric acid), followed by heating at 100 °C for 3 min. Quantitative determination by absorbance measurement at 366 nm. The hRF value for tacrolimus was 20. Linearity was between 20 and 140 ng/zone. Intermediate precisions were below 3 % (n=3). The LOD and LOQ were 6 and 17 ng/zone, respectively. Mean recovery was 101.6 %.

      Classification: 28a
      128 006
      Simultaneous colorimetric sensing of malachite & leucomalachite green in aquatic products based on novel ionic associate self-visualization HPTLC strips
      J. SONG*, S. LAY, D. WANG, X. WU, Y. ZHANG, L. PANG, T. CHAI, J. ZHAO, X. WANG (*School of Agriculture and Food Science, Zhejiang A & F University, Hangzhou 311300, People’s Republic of China, JSong990792357@163.com)

      Sens. Actuators. B. Chem. 325, 128753 (2020). Leucomalachite green (1) and malachite green (2) and certain amount of highly dispersed potassium iodate titanium dioxide composites (0.1 M titanium butoxide was used as a precursor with 5 % potassium iodate solution to prepare KIO3-doped TiO2 nanoparticles). The sample was developed with chloroform - methanol 4:5. Detection by dipping into 5 % potassium iodine, followed by heating and then dipping into a zinc ion solution followed by heating at 80 °C. Linearity was in the range of 0.3–8.0 μg/mL for (1) and 0.1–4.0 μg/mL for (2), respectively. LOD and LOQ were 1.7 and 5.2 μg/kg for (1) and 0.9 and 2.7 μg/kg for (2), respectively.

      Classification: 28a
      128 029
      Identification of type B trichothecenes and zearalenone in Chilean cereals by planar chromatography coupled to mass spectroscopy
      D. JORQUERA, J. PAVON, Gisela RIOS* (*Interdisciplinary Research Laboratory in Mycotoxins, Department of Food Sciences and Technology, Faculty of Pharmacy, University of Concepcion, Barrio Universitario s/n, Concepcion, Chile, grios@udec.cl)

      Food Addit Contam Part A. 38, 1778-1787 (2021). HPTLC of deoxynivalenol (1), 3-acetyldeoxynivalenol (2), 15-acetyldeoxynivalenol (3), zearalenone (4) and nivalenol (5) in Chilean cereals on silica gel with toluene - ethyl acetate - formic acid 1:8:1. Detection by dipping into a solution of 10 % aluminium trichloride in 50% methanol, followed by heating at 120 °C for 15 min. Quantitative determination by absorbance measurement at 366 nm. The hRF values for (1) to (6) were 39, 50, 45, 60 and 20, respectively. Linearity was between 20 and 160 ng/zone for (1) to (5). The LOD and LOQ were 120 and 160 µg/Kg for (1), 120 and 200 µg/kg for (2) and (3), 80 and 120 µg/kg for (4) and 120 and 160 µg/kg for (5), respectively. Recovery was between 88.6 and 111.5 % for (1), 93.6 and 108.3 % for (2), 91.0 and 111.0 % for (3), 84.3 and 114.2 % for (4) and 86.0 and 112.5 % for (5).

      Classification: 28b