Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

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      52 110
      Z
      L. MIZRACHL., L. POLONSKAJA, E. VORONZOV

      chim. 53, 426-430 (1983). (Russian). (Synthesis of esters of isopropylidene glycerine and some phosphoric acids.) TLC on silica with butanol - acetic acid - water 4:1:5 and on alumina with ether - ethanol 20:1. Detection by UV.

      Keywords:
      Classification: 5
      84 024
      Quantitative applications of fluorescence and ultraviolet scanning densitometry for compositional analysis of petroleum products in thin-layer chromatography
      V.L. CEBOLLA*, L. MEMBRADU, M.P. DOMINGO P. HENRION, R. GARRIGA, P. GANZALEZ, F.P. COSSIO, A. ARRETA, J. VELA, (*Dept. Proc. Quim., Inst. Carboquim., CSIC, Maria Luna, 12.50015 Zaragoza, Spain)

      J. Chromatogr. Sci. 37, 219-226 (1999). Presentation of a direct application of the fluorescence response enhancement, derived from the interaction of the berberine cation with saturated hydrocarbons, to petrochemical analysis. Determination of hydrocarbon types in middle and heavy petroleum distillates with adequate precision and sensitivity by TLC on silica with n-hexane, dichloromethane, toluene, respectively. Quantitation of saturates and aromatics by densitometry. Investigation of the effect of the alkane structure on the fluorescent response. Discussion of the influence of various conditions on the reliability of the method. Comparison of the results with those obtained by using other well-established techniques in the area.

      Keywords:
      Classification: 5
      80 026
      Quantitative determination of hydrocarbons in waste water by thin-layer chromatography
      H. ENGELHARDT, P. ENGEL, (Univ. des Saarlandes, Instrumentelle Analytik/Umweltanalytik, D-66123 Saarbrücken, Germany)

      J. Planar Chromatogr. 10, 336-341 (1997). Description of a TLC technique for quantitative determination of hydrocarbons in waste water after extraction with n-heptane by means of a micro separator. TLC on silica with n-heptane and chamber saturation. Quantification by IR spectroscopy or after dyeing with acid violet 17 which gives detection sensitivities lower by at least one magnitude. The proposed technique also enables determination of other groups of potential contaminants by applying multiple step development.

      Keywords:
      Classification: 5a
      119 011
      Linear modeling of the soil-water partition coefficient normalized to organic carbon content by reversed-phase thin-layer chromatography
      F. ANDRI?*, Sandra ŠEGAN, Aleksandra DRAMI?ANIN, Helena MAJSTOROVI?, Dusanka MILOJKOVI?-OPSENICA (*Fac. of Chem., Univ. of Belgrade, Studentski trg 12-16, P.O. Box 51, 11158 Belgrade, Serbia)

      J. Chromatogr. A 1458, 136–144, (2016). The soil-water partition coefficient normalized to the organic carbon content (KOC) influences the fate of organic compounds in the environment. This paper proposes a RP-TLC method for KOC determination as a simpler, yet equally accurate method as the official HPLC method. TLC on different systems, including RP-18 and cyano phases developed with methanol – water and acetonitrile – water mixtures. 50 different compounds such as phenols, benzodiazepines, triazine herbicides, and polyaromatic hydrocarbons were selected. A calibration set of 29 compounds with known logKOC values was used to build simple univariate calibrations, Principal Component Regression (PCR) and Partial Least Squares (PLS) models between logKOC and TLC retention parameters. The models exhibit good statistical performance and indicate that the cyano phase contributes better to logKOC modeling than the RP-18 phase. Comparison of the proposed TLC methods, the official HPLC method, and four in silico estimation approaches by using the non-parametric Sum of Ranking Differences(SRD) approach. The best estimations of logKOC values were achieved by simple univariate calibration of TLC retention data from cyano phase developed with 40–50 % methanol. In a Linear Solvation Energy Relationship study it was found that the more polar cyano phase in combination with methanol – water mixtures is the key to better modeling of logKOC through significant diminishing of dipolar and proton accepting influence of the mobile phase as well as enhancing molar refractivity in excess of the chromatographic systems.

      Keywords: environmental
      Classification: 2d, 5b
      60 046
      (Elution method for preparative thin-layer chromatography)
      X. TIAN (Tian Xingguo), G. SONG (Song Guixia), (Explor. Inst., Daqing Pet. Manage Bur., P.R. China). Chinese J. Chem. (9), 39-41, 36 (1986) (Huaxue Tongbao). (Chinese)

      Preparative TLC of fluoranthene and acenaphthene etc. on silica with n-hexane - petrol-ether and petrol-ether - dichloroethane 6:1. Detection by UV light or densitometry. Elution with THF. Discussion of the conditions.

      Keywords: preparative TLC
      Classification: 5b
      66 043
      (Quantitative HPTLC of polyaromatic hydrocarbons)
      W. FUNK, J. BECKER, V. GLÜCK, (FH Giessen-Friedberg, Dept. Techn. Public Health Serv., Wiesenstrasse 14, D-W-6300 Giessen, Germany)

      Merck Spectrum 1991, 24-28. HPTLC of indenopyrene, benzofluoroanthene, benzopyrene, fluoroanthene, benzoperylene on silica (impregnated with 4 g caffeine in 96 g dichloromethane) at -20°C with dichloromethane as eluent. Quantification by in-situ fluorimetry.

      Classification: 5b
      76 035
      Two-dimensional TLC and fluorescence analysis with CCD video camera used to determine the dissociation of diphenylhexatriene included in ß-cyclodextrin
      J.C. GUILLEUX, K.N. BARNOUIN, F.A. RICCHIERO, D.A. LERNER, (Lab. de Chim. Phys. Informat., Ecole Nation. Superieure de Chim., 34053 Montpellier, France)

      J. Liquid Chromatogr. 17, 2821-2831 (1994). Use of 2-D TLC coupled to fluorescence analysis by CCD video camera for the study of complexes which contain at least one fluorescent component. Application of the method to the diphenylhexatriene ß-cyclodextrin complex in H2O/MeCN system enables the separation of free and bound DPH and an accurate estimation of their respective quantities on the plate. Evaluation of free DPH eluted with the hydrocarbon media by comparison of emitted fluorescence intensity with the linear 0 to 50 pmol calibration scale. Dissociation of DPH bound to BCD with a brief polarmigration followed by elution with a non polar solvent mixture and evaluated as above.

      Keywords:
      Classification: 4e, 5b
      83 030
      Separation of C60 and C70 fullerenes by thin-layer chromatography on silica gel impregnated with polymers
      L.-D. LITVINOVA, V.N. ZGONNIK, (Rus. Acad. of Sci., Inst. of Macromol. Compounds, Bolshoi pr. 31, 199004 St. Petersburg, Russia)

      J. AOAC Int. 82, 117-230 (1999). Investigation of the effect of polymer nature and concentration of impregnating solution on retention factors and separation selectivity. TLC separation of C60 and C70 fullerenes on silica gel impregnated with polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP) and poly(ethylene oxide)(PEO) solutions with hexane. Detection under UV 254 and 366 nm. Results showed that PVA is a potential complex-forming agent for fullerenes.

      Keywords:
      Classification: 5b