Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

  • Full text search: Enter a keyword, e.g. an author's name, a substance, a technique, a reagent or a term and see all related publications
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Registered users can create a tailor made PDF of selected articles throughout CCBS search – simply use the cart icon on the right hand of each abstract to create your individual selection of abstracts. You can export your saved items to PDF by clicking the download icon.

      88 014
      Enhancement of mobile phase velocity in TLC by means of an external alternating electric field
      S. KREIBIK*, V. COMAN, C. MARUROIU, G. MIHAILESCU, S. PRUNEANU, (*Nat. Inst. of Res. and Development for Isotopic and Molecular Technologies, P.O. Box 700, Cluj-Napoca 3400, Romania)

      J. Planar Chromatogr. 14, 355-359 (2001). Increase of velocity and migration distance of the mobile-phase front in porous media by application of an external electric field. TLC on silica gel with benzene - methanol 3:2.

      Keywords:
      Classification: 3d
      92 011
      Planar electrochromatography in horizontal chamber with cooling of the chromatographic plate
      T.H. DZIDO*, R. MAJEWSKI, (*Dept. of Inorg. and Anal. Chem., Med. Univ., Staszica 6, 20-081 Lublin, Poland)

      Proc. Intern. Symp. on Planar Separations Plan. Chrom. 129-138 (2003). Conventional HPTLC of aromatic hydrocarbons with polar groups (2-naphthol, 1-nitro-naphthalene, 1,7-dihydroxynaphthalene, 2-ethylanthraquinone, 4-nitroaniline, anthraquinone) and dyes (1-aminoanthraquinone, fat brown, 4-diethylaminoazobenzene, 4-hydroxybenzene-azonaphthol-2, 4-(4-(N,N-ethylethanol)benzeneazo)-N-methylphthalimide, 4-nitroaniline) on RP-18 with e.g. 90% methanol in pH 10 buffer (diluted 1:7 with water) or acetonitrile - buffer in a presaturated horizontal chamber. Planar electrochromatography was performed under similar conditions with the exception of e.g. using plates with 0.5 cm margins of paraffin oil along their longer parallel edges and pre-wetting after spotting of the sample with mobile phase from both sides leaving within approximately 1 mm dry zone of start spot position. Then the chromatographic plate was pressed face-to-face with a counter-plate using clips. 200-250 V /cm field was applied to the plate. Higher efficiency and shorter development time of electrochromatography systems relative to conventional TLC separations were demonstrated.

      Keywords:
      Classification: 3d
      95 010
      A new instrument for automated multiple development in thin-layer chromatography
      Y. WANG (Yuping Wang), D. WANG* (Dongyuan Wang), J. WANG (Jie Wang), Z. XIONG ( Zhili Xiong), H. ZHANG (Hongxia Zhang), G. SHE, (Gaohong She) J. LI (Jian Li), S. XIAO (Shengtao Xiao) (*Department of Analytical Chemistry, Shenyang Pharmaceutical University, Shenyang, 110016 P. R. China)

      J. Planar Chromatogr. 17, 290-296 (2004). Description of a new AMD instrument. Its main advantages are very low cost both of construction and in use. In comparison with ascending development in conventional instruments, a laboratory-made horizontal sandwich chamber is used for development. With the help of a series of special accessories no obvious mobile phase remains in the distributor after each step thus saving a large amount of solvent. All the components of the instrument are easy to obtain, so the average worker in the laboratory could construct all the instrument except the control unit. An application of the instrument is described; the results obtained were satisfactory. Compared with the commercial instrument the main differences are 1) a horizontal sandwich chamber with funnel distributor is used as development chamber, 2) the most expensive component, a motor-driven valve, is omitted, 3) a micro air pump (normally used to supply oxygen for goldfish) is used to deliver mobile phase to the chamber. AMD separation of 13 dyes with first acetone - ethyl acetate 1:1 to compress the spots to slim bands, then seven steps with ethyl acetate - chloroform 4:21 to1:9 were completed; then seven steps with chloroform - cyclohexane 17:3 to 67:33. After these fifteen steps of AMD the mixture was separated into eighteen visible spots.

      Keywords: AMD
      Classification: 3d
      101 012
      Low cost, efficient TLC sprayer
      P.K. ZARZYCKI*, M B. ZARZYCKA (*Toxicology and Bioanalysis Section, Department of Environmental Biology, Koszalin University of Technology, Sniadeckich 2, 75-453 Koszalin, Poland; pkzarz@wp.pl)

      J. Planar Chromatogr. 21, 221-223 (2008). Construction of a simple and inexpensive compressed air-driven spraying device which can handle small and large volumes of TLC derivatization reagents. The device is made from widely available HPLC accessories, including stainless-steel fittings and tubing, and can be used with corrosive liquids with a wide range of viscosity. TLC of fluorescein, methyl red, bromocresol green, phenolphthalein, and crystal violet on RP-18 with methanol - water 7:3. Evaluation under white light.

      Classification: 3e
      115 013
      A new and sensitive TLC method to measure trans-resveratrol in red wine
      A. LOTZ, Barbara MILZ, B. SPANGENBERG* (*Institute of Process Engineering, University of Offenburg, Badstrasse 24, 77652 Offenburg, Germany, Spangenberg@HSOffenburg.de)

      J. Liq. Chromatogr. Relat. Technol. 38, 1104-1108 (2015). HPTLC of trans-resveratrol on silica gel with ethyl acetate - cyclohexane - n-butanol 9:9:2. Detection through chemiluminescence by dipping into a TCPO solution (250 mg bis(2,4,6-trichlorophenyl)oxalate in 36 mL n-butyl acetate, followed by adding 0.4 mL hydrogen peroxide that was vigorously shaken with the solution for 20 min). The HPTLC plate was covered by a glass plate and measured for 2 min using a very light-sensitive CCD camera. The hRF value for trans-resveratrol was 78. Linearity was in the range of 20-500 ng/zone. LOD and LOQ were 13.7 and 20.3 ng/zone, respectively.

      Classification: 3e, 7
      59 017
      Rubeanic acid
      C.P. GARCIA, (Res.Center, Univ. Santo Tomas, Manila, Philippines)

      J. Chromatogr. 350, 468-470 (1985). TLC of various steroids on silica with chloroform - methanol 10:1. Detection by spraying with 1 % rubeanic acid in concentrated sulfuric acid. Evaluation by densitometry. Detection limits 0.1-0.3 mg for most steroids examined.

      Classification: 3e, 13
      65 074
      Monodansyl cadaverine as a fluorescent marker for carboxylic acids - in situ prechromatographic
      A. JUNKER-BUCHHEIT, H. JORK*, (*Univ. des Saarlandes, Fachbereich 14, D-6600 Saarbrücken, FRG)

      J. Planar Chromatogr. 2, 65-70 (1989). For qualitative analysis monodansyl cadaverine (MDC) was employed without further purification. Column-chromatographic purification is recommended for the quantification of short chain carboxylic acids. For in situ derivatization the carboxylic acid sample solutions were applied to the HPTLC plates as bands with a maximum length of 10 mm. These were then „overlayed“ with MDC solution containing N,N’-dicyclohexylcarbodiimide to activate the acids. Short-chain carboxylic acids were separated on normal silicagel phases with toluene - ethyl acetate - ammonia mixtures as mobile phase. Stepwise and gradient developments allow the baseline separation. Long-chain carboxylic acids are better separated on RP-18 phases with acetonitrile-tetrahydrofuran mixtures and methanol as mobile phase.

      Classification: 3e, 4d, 11a
      70 079
      A new fluorescence detection method for the separation of organic acids by TLC
      C. SARBU*, V. COMAN, C. MARUTOIU, (*Babes-Bolyai Univ., Fac. of Chem., 3400 Cluj-Napoca, Romania)

      J. Planar Chromatogr. 4, 325-326 (1991). TLC of carboxylic acids (no details) on silica impregnated with different concentrations of paraffin oil in petrol ether with acetic acid - acetonitrile 50:1. Detection after drying at 100-120 °C for 30 min. by spraying with a 0.1% dichloromethane or benzene solution of the 2-methyl-, 2-methoxy-, 2-chloro-, 2-bromo-, or 2-fluoro-derivatives of 9-isothiocyanatoacridine (most efficient: 2- methoxy- and 2-chloro-compounds.

      Classification: 3e, 11a