Cumulative CAMAG Bibliography Service CCBS

Our CCBS database includes more than 11,000 abstracts of publications. Perform your own detailed search of TLC/HPTLC literature and find relevant information.

The Cumulative CAMAG Bibliography Service CCBS contains all abstracts of CBS issues beginning with CBS 51. The database is updated after the publication of every other CBS edition. Currently the Cumulative CAMAG Bibliography Service includes more than 11'000 abstracts of publications between 1983 and today. With the online version you can perform your own detailed TLC/HPTLC literature search:

  • Full text search: Enter a keyword, e.g. an author's name, a substance, a technique, a reagent or a term and see all related publications
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      79 010
      Relationship between structure and reversed-phase thin-layer chromatographic lipophilicity parameters in a group of piperazine derivatives
      P. KASTNER*, M. KUCHAR, J. KLINMES, D. DOSEDLOVA, (*Pharm. Fac. Charles Univ., Dept. Pharm. Chem. & Drug Cont., Heyrovskeho 1203, 50005 Hradec Kralove, Czech Rep.)

      J. Chromatogr. A 766, 165-170 (1997). Determination of the RM values of substituted piperazine derivatives on silanized silica with buffered aqueous acetone with or without n-octylamine. Comparison of the difference between the chromatographically determined lipophilicity of substances containing aromatic nuclei that are separated by a sufficiently flexible chain and that calculated on the basis of tabulated fragmental constants.

      Keywords:
      Classification: 2c
      81 051
      Normal and reversed-phase TLC of some hydrazine derivatives
      G. IONITA*, T. CONSTANTINESCU, P. IONITA, (*Dept. of Phys. Chem., Gh. Doja Street 41, 0300 Pitesti, Romania)

      J. Planar Chromatogr. 11, 141-144 (1998). TLC of 26 compounds derived from 1,2-diphenylhydrazine (half of which were stable free radicals) on silica gel or alumina with toluene and on silica gel impregnated with paraffin oil with different mixtures of water, acetone, and 2-propanol. Detection by direct observation. Rf values, lipophilicities, and specific lipophilic surface areas were determined. Simple, inexpensive, quick, and sensitive TLC procedure.

      Classification: 2c, 17a
      84 011
      Retention behavior of some phenols and anilines on CN-, DIOL-, and silica precoated HPTLC plates
      M. WAKSMUNDZKA-HAJNOS, A. PETRUCZYNIK, (Dept. of Inorg. and Anal. Chem., Med. Univ., Staszica 6, 20-081 Lublin, Poland)

      J. Liq. Chrom. & Rel. Technol. 22, 51-75 (1999). Examination of the retention behavior of 13 phenols and 19 aromatic amines on modified TLC plates using normal-phase eluent systems (polar modifier (2-propanol, ethyl methyl ketone, dioxane, tetrahydrofuran, diisopropyl ether) in n-heptane) and comparison of the results with those obtained on bare silica gel. - Visualization under UV 254 nm.

      Keywords:
      Classification: 2c
      87 004
      Inclusion planar chromatography of enantiomeric and racemic compounds
      L. LEPRI, M. Del BUBBA, A. CINCINELLI, L. BODDI*, (Dept. of Public Health, Epidemiology and Env. Anal. Chem., Univ. of Florence, Via G. Capponi 9, 50121 Florence, Italy)

      J. Planar Chromatogr. 13, 384-387 (2000). TLC of enantiomers (1-acenaphthol, phenoxymethyl oxirane, 4-chlorophenoxymethyl oxirane, 2-methylphenoxymethyl oxirane, trityloxymethyl oxirane) on microcrystalline cellulose triacetate (MCTA) with 2-propanol - water resp. ethanol - water 4:1 or of 7 glycidyl ethers with mobile phases containing derivatized and underivatized cyclodextrins on chiral stationary phases. Detection under UV 254 and 366 nm. Quantitation by densitometry in reflectance mode at 254 nm.

      Keywords:
      Classification: 2c, 38
      94 001
      Interaction between cholesterol and non-ionic surfactants studied by thin-layer chromatography
      E. FORGÁCS*, T. CSERHÁTI, O. FARKAS, A. ECKHARDT, I. MIKSIK, Z. DEYL (*Research Laboratory of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P. O. Box 17, 1525 Budapest, Hungary)

      J. Liq. Chrom. Rel. Technol. 27, 1981-1992 (2004). Study of the interaction between cholesterol and non-ionic surfactants by reversed-phase TLC using cholesterol-impregnated TLC plates and methanol - water mixtures. TLC on aluminum oxide impregnated by overnight pre-development in a solution of cholesterol dissolved in chloroform - acetone 1:1. 20 surfactants were tested (Arcopal, Sapogenat, Tween, Genapol, Myrj, and Brij). The intercept obtained from linear regression anal. (RM0), being characteristic for the strength of interaction, and the slope (b), being related to the surface area of surfactants in contact with cholesterol, were detected. Stepwise regression anal. (SRA) was performed to find relation between the structural parameters of surfactants and strength of interaction. Stacking interaction exists between cholesterol and the aromatic ring of the surfactants. The number of ethylene oxide units and length of the carbon chain in the surfactant molecules have significant effect on the strength of the interaction between the compounds studied.

      Classification: 2c
      96 114
      A comparative study of the lipophilicity of benzimidazole and benztriazole derivatives by RPTLC
      T. Lj. Djakovic-Sekulic, C. Sarbu, Nada U. Perisic-Janjic* (*Department of Chemistry, Faculty of Science, University of Novi Sad,Trg D. Obradovica 3, 21000 Novi Sad, Serbia and Montenegro)

      J. Planar Chromatogr. 18, 432-436 (2005). TLC of nine benzimidazole and benztriazole derivatives on silica gel impregnated with paraffin oil with methanol - water mixtures. After development the plates were dried and examined under UV light at 254 nm. A quantitative structure-retention relationship (QSRR) correlation study was performed.

      Classification: 2c, 32a
      103 007
      Prediction of the retention in thin layer chromatography screening systems by atomic contributions
      L. KOMSTA (Department of Medicinal Chemistry, Skubiszewski Medical University, Jaczewskiego 4, 20-090 Lublin, Poland)

      Anal. Chim. Acta 593 (2), 224-237 (2007). Presentation of a novel atomic-contribution system for predicting RM values by TLC on silica gel with 13 screening systems where the large experimental datasets (198-761 RM values) are available. RM values could be predicted with less than 0.5 % error in the majority of solutes (besides several outliers), which corresponds to an hRf value difference of 28 in the worst case. Validation of the system by dividing the data into training and validation datasets, proving its accuracy. The main reason for outliers were large conjugated heterocycles, quarternary ammonium cations, large amount of polar atoms or very simple but unique molecules. The method invloves easy manual calculation and no need for a software. It was applied to predict retention of new compounds in existing chromatographic screening systems.

      Classification: 2c
      112 007
      (E)-2-benzylidenebenzocyclanones
      Z. ROZMER, P. PERJESI* (*Institute of Pharmaceutical Chemistry, University of Pécs, Rókus u. 2, 7624 Pécs, Hungary, pal.perjesi@aok.pte.hu)

      determination of log P of (E)-3-benzylidene-2,3-dihydro-1-benzopyran-4-ones by RP-TLC. Effect on log P of incorporation of oxygen atom into carbocyclic chalcone analogues. J. Planar Chromatogr. 26, 284-288 (2013). Log P-TLC of (E)-3-benzylidene-2,3-dihydro-1-benzopyran-4-ones on silica gel with methanol - water 3:2. Detection under UV light at 254 nm. The effect of positions (ortho, meta, and para) of the aromatic substituents in the compounds was evaluated.

      Classification: 2c